Risk Phrases
Indication of Particular Risks
| R1: | Explosive when dry |
| 2: | Risk of explosion by shock, friction, fire or other sources of ignition |
| 3: | Extreme risk of explosion by shock, friction, fire or other sources of ignition |
| 4: | Forms very sensitive explosive metallic compounds |
| 5: | Heating may cause an explosion |
| 6: | Explosive with or without contact with air |
| 7: | May cause fire |
| 8: | Contact with combustible material may cause fire |
| 9: | Explosive when mixed with combustible material |
| 10: | Flammable |
| 11: | Highly Flammable |
| 12: | Extremely Flammable |
| 14: | Reacts violently with water |
| 15: | Contact with water liberates extremely flammable gases |
| 16: | Explosive when mixed with oxidizing substances |
| 17: | Spontaneously flammable in air |
| 18: | In use may form flammable/explosive vapor-air mixture |
| 19: | May form explosive peroxides |
| 20: | Harmful by inhalation |
| 21: | Harmful in contact with skin |
| 22: | Harmful if swallowed |
| 23: | Toxic by inhalation |
| 24: | Toxic in contact with skin |
| 25: | Toxic if swallowed |
| 26: | Very Toxic by inhalation |
| 27: | Very Toxic in contact with skin |
| 28: | Very Toxic if swallowed |
| 29: | Contact with water liberates toxic gas |
| 30: | Can become highly flammable in use |
| 31: | Contact with acids liberates toxic gas |
| 32: | Contact with acids liberates very toxic gas |
| 33: | Danger of cumulative effects |
| 34: | Causes burns |
| 35: | Causes severe burns |
| 36: | Irritating to the eyes |
| 37: | Irritating to the respiratory system |
| 38: | Irritating to the skin |
| 39: | Danger of very serious irreversible effects |
| 40: | Limited evidence of a carcinogenic effect |
| 41: | Risk of serious damage to eyes |
| 42: | May cause sensitization by inhalation |
| 43: | May cause sensitization by skin contact |
| 44: | Risk of explosion if heated under confinement |
| 45: | May cause cancer |
| 46: | May cause heritable genetic damage |
| 48: | Danger of serious damage to health by prolonged exposure |
| 49: | May cause cancer by inhalation |
| 50: | Very Toxic to aquatic organisms |
| 51: | Toxic to aquatic organisms |
| 52: | Harmful to aquatic organisms |
| 53: | May cause long-term adverse effects in the aquatic environment |
| 54: | Toxic to flora |
| 55: | Toxic to fauna |
| 56: | Toxic to soil organisms |
| 57: | Toxic to bees |
| 58: | May cause long-term adverse effects in the environment |
| 59: | Dangerous for the ozone layer |
| 60: | May impair fertility |
| 61: | May cause harm to the unborn child |
| 62: | Possible risk of impaired fertility |
| 63: | Possible risk of harm to the unborn child |
| 64: | May cause harm to breast-fed babies |
| 65: | Harmful: May cause lung damage if swallowed |
| 66: | Repeated exposure may cause skin dryness or cracking |
| 67: | Vapors may cause drowsiness and dizziness |
| 68: | Possible risk of irreversible effects |
Combination of Particular Risks
| R14/15: | Reacts violently with water, liberating extremely flammable gases |
| 15/29: | Contact with water liberates toxic, extremely flammable gas |
| 20/21: | Harmful by inhalation and in contact with skin |
| 20/21/22: | Harmful by inhalation, in contact with skin and if swallowed |
| 20/22: | Harmful by inhalation and if swallowed |
| 21/22: | Harmful in contact with skin and if swallowed |
| 23/24: | Toxic by inhalation and in contact with skin |
| 23/24/25: | Toxic by inhalation, in contact with skin and if swallowed |
| 23/25: | Toxic by inhalation and if swallowed |
| 24/25: | Toxic in contact with skin and if swallowed |
| 26/27: | Very Toxic by inhalation and in contact with skin |
| 26/27/28: | Very Toxic by inhalation, in contact with skin and if swallowed |
| 26/28: | Very Toxic by inhalation and if swallowed |
| 27/28: | Very Toxic in contact with skin and if swallowed |
| 36/37: | Irritating to eyes and respiratory system |
| 36/37/38: | Irritating to eyes, respiratory system and skin |
| 36/38: | Irritating to eyes and skin |
| 37/38: | Irritating to respiratory system and skin |
| 39/23: | Toxic: danger of very serious irreversible effects through inhalation |
| 39/23/24: | Toxic: danger of very serious irreversible effects through inhalation in contact with skin |
| 39/23/24/25: | Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed |
| 39/23/25: | Toxic: danger of very serious irreversible effects through inhalation and if swallowed |
| 39/24: | Toxic: danger of very serious irreversible effects in contact with skin |
| 39/24/25: | Toxic: danger of very serious irreversible effects in contact with skin and if swallowed |
| 39/25: | Toxic: danger of very serious irreversible effects if swallowed |
| 39/26: | Very Toxic: danger of very serious irreversible effects through inhalation |
| 39/26/27: | Very Toxic: danger of very serious irreversible effects through inhalation and in contact with skin |
| 39/26/27/28: | Very Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed |
| 39/26/28: | Very Toxic: danger of very serious irreversible effects through inhalation and if swallowed |
| 39/27: | Very Toxic: danger of very serious irreversible effects in contact with skin |
| 39/27/28: | Very Toxic: danger of very serious irreversible effects in contact with skin and if swallowed |
| 39/28: | Very Toxic: danger of very serious irreversible effects if swallowed |
| 42/43: | May cause sensitization by inhalation and skin contact |
| 48/20: | Harmful: danger of serious damage to health by prolonged exposure through inhalation |
| 48/20/21: | Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin |
| 48/20/21/22: | Harmful: danger of serious damage to health by prolonged exposure through inhalation, and in contact with skin and if swallowed |
| 48/20/22: | Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed |
| 48/21: | Harmful: danger of serious damage to health by prolonged exposure in contact with skin |
| 48/21/22: | Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed |
| 48/22: | Harmful: danger of serious damage to health by prolonged exposure if swallowed |
| 48/23: | Toxic: danger of serious damage to health by prolonged exposure through inhalation |
| 48/23/24: | Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin |
| 48/23/24/25: | Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed |
| 48/23/25: | Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed |
| 48/24: | Toxic: danger of serious damage to health by prolonged exposure in contact with skin |
| 48/24/25: | Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed |
| 48/25: | Toxic: danger of serious damage to health by prolonged exposure if swallowed |
| 50/53: | Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment |
| 51/53: | Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment |
| 52/53: | Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment |
| 68/20: | Harmful: possible risk of irreversible effects through inhalation |
| 68/20/21: | Harmful: possible risk of irreversible effects through inhalation and in contact with skin |
| 68/20/21/22: | Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed |
| 68/20/22: | Harmful: possible risk of irreversible effects through inhalation and if swallowed |
| 68/22: | Harmful: possible risk of irreversible effects if swallowed |
| 68/21: | Harmful: possible risk of irreversible effects in contact with skin |
| 68/21/22: | Harmful: possible risk of irreversible effects in contact with skin and if swallowed |
| 68/22: | Harmful: possible risk of irreversible effects if swallowed |
Safety Phrases
Indication of Safety Precautions
| S1: | Keep locked up |
| 2: | Keep out of the reach of children |
| 3: | Keep in a cool place |
| 4: | Keep away from living quarters |
| 5: | Keep contents under ... (appropriate liquid to be specified by the manufacturer) |
| 6: | Keep under ... (inert gas to be specified by the manufacturer) |
| 7: | Keep container tightly closed |
| 8: | Keep container dry |
| 9: | Keep container in a well-ventilated place |
| 12: | Do not keep the container sealed |
| 13: | Keep away from food, drink and animal feeding stuffs |
| 14: | Keep away from ... (incompatible materials to be indicated by the manufacturer) |
| 15: | Keep away from heat |
| 16: | Keep away from sources of ignition - No smoking |
| 17: | Keep away from combustible material |
| 18: | Handle and open container with care |
| 20: | When using, do not eat or drink |
| 21: | When using, do not smoke |
| 22: | Do not breathe dust |
| 23: | Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) |
| 24: | Avoid contact with skin |
| 25: | Avoid contact with eyes |
| 26: | In case of contact with eyes, rinse immediately with plenty of water and seek medical advice |
| 27: | Take off immediately all contaminated clothing |
| 28: | After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) |
| 29: | Do not empty into drains |
| 30: | Never add water to this product |
| 33: | Take precautionary measures against static discharges |
| 35: | This material and its container must be disposed of in a safe way |
| 36: | Wear suitable protective clothing |
| 37: | Wear suitable gloves |
| 38: | In case of insufficient ventilation, wear suitable respiratory equipment |
| 39: | Wear eye/face protection |
| 40: | To clean the floor and all objects contaminated by this material use ... (to be specified by the manufacturer) |
| 41: | In case of fire and/or explosion do not breathe fumes |
| 42: | During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified) |
| 43: | In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water) |
| 45: | In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) |
| 46: | If swallowed, seek medical advice immediately and show this container or label |
| 47: | Keep at temperature not exceeding ... E C (to be specified by the manufacturer) |
| 48: | Keep wetted with ... (appropriate material to be specified by the manufacturer) |
| 49: | Keep only in the original container |
| 50: | Do not mix with ... (to be specified by the manufacturer) |
| 51: | Use only in well-ventilated areas |
| 52: | Not recommended for interior use on large surface areas |
| 53: | Avoid exposure - obtain special instruction before use |
| 56: | Dispose of this material and its container to hazardous or special waste collection point |
| 57: | Use appropriate container to avoid environmental contamination |
| 59: | Refer to manufacturer/supplier for information on recovery/recycling |
| 60: | This material and/or its container must be disposed of as hazardous waste |
| 61: | Avoid release to the environment. Refer to special instructions safety data sheet |
| 62: | If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label |
| 63: | In case of accident by inhalation, remove casualty to fresh air and keep at rest |
| 64: | If swallowed, rinse mouth with water (only if the person is conscious) |
Combination of Safety Precautions
| 1/2: | Keep locked up and out of the reach of children |
| 3/7: | Keep container tightly closed in a cool place |
| 3/9/14: | Keep in a cool well-ventilated place away from ... (incompatible materials to be indicated by manufacturer) |
| 3/9/14/49: | Keep only in the original container in a cool well-ventilated place away from ... (incompatible materials to be indicated by manufacturer) |
| 3/9/49: | Keep only in the original container in a cool well-ventilated place |
| 3/14: | Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer) |
| 7/8: | Keep container tightly closed and dry |
| 7/9: | Keep container tightly closed and in a well-ventilated place |
| 7/47: | Keep container tightly closed and at a temperature not exceeding ... °C (to be specified by manufacturer) |
| 20/21: | When using, do not eat, drink or smoke |
| 24/25: | Avoid contact with skin and eyes |
| 27/28: | After contact with skin, take off immediately all contaminated clothing and wash imediately with plenty of.... (to be specified by the manufacturer) |
| 29/35: | Do not empty into drains, dispose of this container and it's material in a safe way |
| 29/56: | Do not empty into drains, dispose of this material and its container to hazardous or special waste-collection point |
| 36/37: | Wear suitable protective clothing and gloves |
| 36/37/39: | Wear suitable protective clothing, gloves and eye/face protection |
| 36/39: | Wear suitable protective clothing and eye/face protection |
| 37/39: | Wear suitable gloves and eye/face protection |
| 47/49: | Keep only in the original container at temperature not exceeding ... °C (to be specified by manufacturer |
PICTOGRAMS AND HAZARD CODES
